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郑州大学化学与分子工程学院导师:段征正文
姓名:段征 性别:男 出生年月:1973年
职称:教授 学院:化学与分子工程学院 最后学历:药学博士
联系方式:郑州市科学大道号郑州大学化学系,郑州市,450001
Email: duanzheng@zzu.edu.cn
主要研究领域:有机磷化学,有机合成方法学、金属有机化学。
段征, 男, 1973年生, 药学博士,教授,河南省高等学校青年骨干教师,河南省教育厅学术技术带头人,中法有机磷功能材料实验室副主任(郑州大学,CNRS-Université de Rennes 1)。1995年郑州大学化学系本科毕业,1998年河南师范大学化学系,河南省化学研究所硕士毕业。2002年日本北海道大学药学部药学博士。2002-2003年日本北海道大学触媒研究中心 博士后。2004-2005年美国加州大学河滨分校化学系博士后。2005年郑州大学化学系教授,2009年中法有机磷功能材料实验室副主任(郑州大学,CNRS-Université de Rennes 1)。2009.10-11法国雷恩一大访问教授(CNRS-Université de Rennes 1)。
主要发表文章
1. Huaiqiu Wang, Chuan Li, Dingjin Geng, Hui Chen, Zheng Duan,* François Mathey*A New Versatile Route for the Conversion of Phospholes into Phosphinines Chem. Eur.J. 2010, published online.
2. Congbao Huang, Hui Liu, Jianzhen Zhang, Zheng Duan* , François Mathey* Dimethyl Acetylenedicarboxylate and Phospholes: A Variety of Reaction Pathways Eur.J.Org.Chem., 2010, published online.
3. Francois Mathey*, 段征*低配位有机磷化学研究概况 中国科学:化学, 2010,40, 888-892.(Francois Mathey*, Zheng Duan*, A concise review of low coordinated organophosphorus compounds, Sci. China Ser.B 2010,40, 888-892. invited paper)
4. Rongqiang Tian, Hui Liu, Zheng Duan,* Francois Mathey*The Abnormal Hydrolysis of 7-Phosphanorbornenium Salts: A Case of Phosphonium-Phosphenium Equivalence J. Am. Chem.Soc., 2009, 131, 16008-16009.
5. Rongqiang Tian, Zheng Duan,* Xiaoxu Zhou, Dingjin Geng, Yangjie Wu and Francois Mathey*Phosphole-N-phenylmaleimide [4+2] cycloadducts as synthetic equivalents of nucleophilic phosphinidenes Chem.Commun., 2009, 2589-2590.
6. Gerui Ren,Jinli Zhang,Zheng Duan,Mengjun Cui,Yangjie Wu* A Simple and Economic Synthesis of Propargylamines by CuI-Catalyzed Three-Component Coupling Reaction with Succinic Acid as Additive. Aust. J. Chem. 2009, 62, 75-81.
7. Zhong Xian Li, Zheng Duan *, Yang Jie Wu *FeCl3 catalyzed diarylmethanes formations Chin. Chem. Lett., 2009, 20, 511-513.
8. Zheng Duan*, Jianzhen Zhang, Rongqiang Tian, Liuying Bai, and Francois Mathey* Reinvestigation of the Reactions of 1-Phenyl-3,4-dimethylphosphole with Dimethyl Acetylenedicarboxylate Organometallics 2008, 27, 5169–5171
9. Zhongxian Li, Zheng Duan*, Huaiqiu Wang, Rongqiang Tian, Qianrui Zhu and Yangjie Wu* An Efficient Iodine-Catalyzed Benzylation Reaction of 1,3-Dicarbonyl Compounds Synlett 2008, 4, 2535–2539.
10. Yi-nan Cheng, Zheng Duan,* Liujian Yu, Zhongxian Li, Yu Zhu, Yangjie Wu* Palladium-Catalyzed Three-Component Arylcyanation of Internal Alkynes with Aryl Bromides and K4[Fe(CN)6] Organic Lett., 2008, 10, 901-904.
11. Zhongxian Li, Zheng Duan*, Jianxun Kang, Huaiqiu Wang, Liujian Yu, Yangjie Wu*A simple access to triarylmethane derivatives from aromatic aldehydes and electron-rich arenes catalyzed by FeCl3 Tetrahedron, 2008, 64, 1924-1930
12. Zheng Duan, Magali Clochard, Bruno Donnadieu, Francüois Mathey,* and Fook S. Tham Synthesis and X-ray Crystal Structure of a P-Confused Carbaporphyrinoid Organometallics, 2007, 26, 3617-3620.
13. Zheng Duan*, Xuejie Xuan, Yangjie Wu* FeCl3 catalyzed addition of activated methylenes to styrene derivatives under air Tetrahedron Lett., 2007, 48, 5157–5159
14. Yi-nan Cheng, Zheng Duan,* Ting Li, Yangjie Wu* Palladium catalyzed Cyanation of Aryl Bromides with Potassium Hexacynoferrate(II) Lett. Org. Chem., 2007, 4, 352-356.
15. Yi-nan Cheng, Zheng Duan,* Ting Li, Yangjie Wu* Cyanation of Aryl Chlorides with Potassium Hexacyanoferrate(II) Catalyzedby Cyclopalladated Ferrocenylimine Tricyclohexylphosphine Complexes Synlett 2007, 4, 543–546
16. Zheng Duan,* Xuejie Xuan, Ting Li, Chenfei Yang and Yangjie Wu*Cerium(IV) ammonium nitrate (CAN) catalyzed aza-Michael addition of amines to α,β-unsaturated electrophiles
Tetrahedron Lett., 2006, 47, 5433–5436
17. Ning Ma, Zheng Duan ,Yangjie Wu* DAB-Cy as an inexpensive and effective ligand for palladium-catalyzed homocoupling reaction of aryl halides
J.Organomet. Chem., 2006,691,5697-5700
18. Zheng Duan, Takahiro Nishimoto, Masamichi Ogasawara, and Tamotsu Takahashi Diallene Formation by Copper(I)-Mediated Reaction of Zirconacyclopentanes with Propargyl Halides Synthesis. 2005, 2055-2060
19. Zheng Duan, Bruno Donnadieu, Francois Mathey An access to original 3, 3-bis(phospholyl)lactones J.Organometallic.Chem., 2005, 690, 450-453
20. Takashi Seki, Yoshinori Noguchi, Duan Zheng, Wen-hua Sun and Tamotsu TakahashiReaction of zirconacyclopentadienes with electrophiles such as benzaldehyde, methacrylate and1-bromo-2-butyne after treatment with RLiTetrahedron Lett., 2004, 45, 9041-9043.
21. Zheng Duan, Kiyohiko Nakajima and Tamotsu Takahashi.Naphthalene formation by allylation of zirconaindenes in the ZnX2-Pd(PPh3)4 system.Chem.Commun., 2001, 1672-1673.
22. Zheng Duan, Wen-Hua Sun, Yuanhong Liu and Tamotsu Takahashi.Formation of cyclopentadiene derivatives by reaction of zirconacyclopentadienes with 1, 1-dihalo compounds.
Tetrahedron Let t, 2000, 41, 7471-7474.
23. Tamotsu Takahashi, Wen-Hua Sun, Zheng Duan and Baojian Shen.Preparation of benzocycloheptene derivatives from zirconacyclopentadienes.Organic Lett., 2000, 2, 1197-1199.
专利
1. 段征,吴养洁, 程绎南,李挺,二茂铁亚胺环钯配合物催化下芳基腈类衍生物的合成方法,申请号:200610048481.9,专利号:ZL200610048481.9
2. 段征, 吴养洁, 李中贤,三芳基甲烷及衍生物的合成方法,申请号:200710054325.8,专利号:ZL 200710054325.8
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